Carbon鈭扴ulfur Bond Formation via Iridium-Catalyzed Asymmetric Allylation of Aliphatic Thiols

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• 作者：Ning Gao ; Shengcai Zheng ; Weikang Yang ; Xiaoming Zhao
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：March 18, 2011
• 年：2011
• 卷：13
• 期：6
• 页码：1514-1516
• 全文大小：708K
• 年卷期：v.13,no.6(March 18, 2011)
• ISSN：1523-7052

文摘

An iridium-catalyzed regio- and enatioselective allylation with aliphatic thiols as the nucleophile in dichloromethane has been accomplished; and the branch products were obtained in 34鈭?0% yields with up to 94/6 b/l and 98% ee.