Visible-Light-Induced Photocatalytic Aerobic Oxidative Csp3–H Functionalization of Glycine Derivatives: Synthesis of Substituted Quinolines

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• 作者：Xiaorong Yang ; Liqi Li ; Ying Li ; Yuan Zhang
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：December 16, 2016
• 年：2016
• 卷：81
• 期：24
• 页码：12433-12442
• 全文大小：511K
• ISSN：1520-6904

文摘

A visible-light induced photocatalytic aerobic oxidative dehydrogenative coupling/aromatization tandem reaction of glycine esters with unactivated alkenes has been accomplished. This visible light-driven protocol has been successfully applied to a broad scope of glycine esters and simple alkenes, giving rise to diverse substituted quinoline derivatives in 18–84% yield under mild (at room temperature under air atmosphere) and operationally simple reaction conditions.