Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin鈥揝ulfoxide Ligands

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• 作者：Feng Xue ; Dongping Wang ; Xincheng Li ; Boshun Wan
• 刊名：The Journal of Organic Chemistry
• 出版年：2012
• 出版时间：April 6, 2012
• 年：2012
• 卷：77
• 期：7
• 页码：3071-3081
• 全文大小：409K
• 年卷期：v.77,no.7(April 6, 2012)
• ISSN：1520-6904

文摘

An efficient rhodium/olefin鈥搒ulfoxide catalyzed asymmetric conjugate addition of organoboronic acids to a variety of nitroalkenes has been developed, where 2-methoxy-1-naphthyl sulfinyl functionalized olefin ligands have shown to be highly effective and are applicable to a broad scope of aryl, alkyl, and heteroaryl nitroalkenes.