Polydopamine-Coated, Nitrogen-Doped, Hollow Carbon鈥揝ulfur Double-Layered Core鈥揝hell Structure for Improving Lithium鈥揝ulfur Batteries
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- 作者：Weidong Zhou ; Xingcheng Xiao ; Mei Cai ; Li Yang
- 刊名：Nano Letters
- 出版年：2014
- 出版时间：September 10, 2014
- 年：2014
- 卷：14
- 期：9
- 页码：5250-5256
- 全文大小：427K
- ISSN：1530-6992
文摘
To better confine the sulfur/polysulfides in the electrode of lithium鈥搒ulfur (Li/S) batteries and improve the cycling stability, we developed a double-layered core鈥搒hell structure of polymer-coated carbon鈥搒ulfur. Carbon鈥搒ulfur was first prepared through the impregnation of sulfur into hollow carbon spheres under heat treatment, followed by a coating polymerization to give a double-layered core鈥搒hell structure. From the study of scanning transmission electron microscopy (STEM) images, we demonstrated that the sulfur not only successfully penetrated through the porous carbon shell but also aggregated along the inner wall of the carbon shell, which, for the first time, provided visible and convincing evidence that sulfur preferred diffusing into the hollow carbon rather than aggregating in/on the porous wall of the carbon. Taking advantage of this structure, a stable capacity of 900 mA h g鈥? at 0.2 C after 150 cycles and 630 mA h g鈥? at 0.6 C after 600 cycles could be obtained in Li/S batteries. We also demonstrated the feasibility of full cells using the sulfur electrodes to couple with the silicon film electrodes, which exhibited significantly improved cycling stability and efficiency. The remarkable electrochemical performance could be attributed to the desirable confinement of sulfur through the unique double-layered core鈥搒hell architectures.