Directing the Conformation of Oligo(phenylenevinylene) Polychromophores with Rigid, Nonconjugatable Morphons

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• 作者：Xinju Zhu ; Beiyue Shao ; David A. Vanden Bout ; Kyle N. Plunkett
• 刊名：Macromolecules
• 出版年：2016
• 出版时间：May 24, 2016
• 年：2016
• 卷：49
• 期：10
• 页码：3838-3844
• 全文大小：451K
• 年卷期：0
• ISSN：1520-5835

文摘

The synthesis and morphological investigation of a series of polychromophore polymers composed of oligomeric bis(2-ethylhexyl)-p-phenylenevinylene (BEH-PPV) (trimer, pentamer, and heptamer) monomers copolymerized with rigid morphological directing groups (morphons) are described. The polymerization was carried out using a Sonogashira cross-coupling polymerization between monomers composed of an iodo-terminated BEH-PPV oligomer and a bis(phenylacetylene)-containing morphon. The rigid morphons are prepared from adamantane and diamantane frameworks that are composed solely of sp³ carbons, inhibit conjugation between BEH-PPV oligomers, and direct the local polymer morphology in either a bent or linear vector, respectively. The morphological properties of the polychromophore polymers were interrogated via single molecule fluorescence spectroscopy, thin-film absorption and fluorescence spectroscopy, and atomic force microscopy. Significant morphological variation was found upon substituting the morphon, as well as the chromophore size, with the most ordered structures being accessed with diamantane morphons.