Hybrid Mesoporous Silica Based on Hyperbranch-Substrate Nanonetwork as Highly Efficient Adsorbent for Water Treatment

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• 作者：Jin Tao ; Jiaqing Xiong ; Chenlu Jiao ; Desuo Zhang ; Hong Lin ; Yuyue Chen
• 刊名：ACS Sustainable Chemistry & Engineering
• 出版年：2016
• 出版时间：January 4, 2016
• 年：2016
• 卷：4
• 期：1
• 页码：60-68
• 全文大小：516K
• ISSN：2168-0485

文摘

Hybrid mesoporous silica based on a hyperbranch-substrate nanonetwork as highly efficient adsorbent was explored by an efficient and facile approach combined with one-pot condensation and grafting-to methodology, including a terminated amino hyperbranched polymer (HBP) modification. The specific synthesis procedure involves the following steps: (i) premodification of SBA-15 via a co-condensation-hydrolysis route, obtaining carboxyl functionalized SBA-15 (SBA-CAR), and (ii) grafting HBP onto SBA-CAR by a grafting-to method, obtaining hybrid mesoporous silica (SBA-HBP). The main structural characteristics of SBA-15 are preserved in the resultant SBA-HBP, which exhibits high surface area, large pore volume, and well-ordered porosity made up of uniform mesopores. Due to its reusability and with a three-dimensional hyperbranch-substrate nanonetwork with substantial functional groups, the as-synthesized SBA-HBP is considered a versatile and sustainable adsorbent for dyes (i.e., methylene blue and congo red) and heavy metal ions (i.e., Cu²⁺ and Fe³⁺) from aqueous media with high adsorption capacity and quick adsorption rate. Also, the saturated adsorption capacities are 452.1 mg/g for MB, 593.4 mg/g for CR, 224.2 mg/g for Fe³⁺, and 158.7 mg/g for Cu²⁺, respectively.