Synthesis of Pincer Hydrido Ruthenium Olefin Complexes for Catalytic Alkane Dehydrogenation

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• 作者：Yuxuan Zhang ; Huaquan Fang ; Wubing Yao ; Xuebing Leng ; Zheng Huang
• 刊名：Organometallics
• 出版年：2016
• 出版时间：January 25, 2016
• 年：2016
• 卷：35
• 期：2
• 页码：181-188
• 全文大小：449K
• ISSN：1520-6041

文摘

A series of new hydrido Ru(II) olefin complexes supported by isopropyl-substituted pincer ligands have been synthesized and characterized. These complexes are thermally robust and active for catalytic transfer and acceptorless alkane dehydrogenation. Notably, the alkane dehydrogenation catalysts are tolerant of a number of polar functional species.