Phosphorothiolation of Aryl Boronic Acids Using P(O)H Compounds and Elemental Sulfur

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• 作者：Jian Xu ; Liangliang Zhang ; Xueqin Li ; Yuzhen Gao ; Guo Tang ; Yufen Zhao
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：March 18, 2016
• 年：2016
• 卷：18
• 期：6
• 页码：1266-1269
• 全文大小：367K
• ISSN：1523-7052

文摘

The first multicomponent reaction (MCR) involving aryl boronic acids, elemental sulfur, and P(O)H compounds is presented. It proceeds with excellent yields and provides an attractive approach for the construction of valuable S-aryl phosphorothioates and S-aryl phosphorodithioates using a one-step strategy. Moreover, this method can be easily adapted to large-scale preparation.