Synthesis and Characterization of an Open Framework Gallium Selenide: Ga4Se7(en)2·(enH)2

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• 作者：Yajie Dong ; Qing Peng ; Ruji Wang ; and Yadong Li
• 刊名：Inorganic Chemistry
• 出版年：2003
• 出版时间：March 24, 2003
• 年：2003
• 卷：42
• 期：6
• 页码：1794 - 1796
• 全文大小：98K
• 年卷期：v.42,no.6(March 24, 2003)
• ISSN：1520-510X

文摘

An open framework gallium selenide, Ga₄Se₇(en)₂·(enH)₂, has beenprepared by the direct reaction of gallium (Ga) and selenium (Se)in ethylenediamine (en), in which both covalent and hydrogenbonds have been employed to combine the inorganic structuresand organic spacers to build layers with micropores. Its structurehas been determined by X-ray diffraction. Its thermal and opticalproperties have been characterized by TGA and UV-vis, Raman,and IR spectroscopies, respectively.