High Pressure Synthesis and Superconductivity of the Ternary Compounds Mg(Mg1鈥?i>xAlx)Si with the Anticotunnite Structure

详细信息    查看全文

• 作者：Shidong Ji ; Masashi Tanaka ; Shuai Zhang ; Shoji Yamanaka
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：October 1, 2012
• 年：2012
• 卷：51
• 期：19
• 页码：10300-10305
• 全文大小：339K
• 年卷期：v.51,no.19(October 1, 2012)
• ISSN：1520-510X

文摘

Ternary compounds Mg(Mg_1鈥?i>xAl_x)Si (0.3 < x < 0.8) have been prepared under high pressure and high temperature conditions of 5 GPa at 800鈥?100 掳C. The single crystal study revealed that the compound (x = 0.45) is isomorphous with the anticotunnite, or the TiNiSi structure, and crystallizes with space group Pnma, with lattice parameters a = 6.9242(2), b = 4.1380(1), c = 7.9618(2) 脜, and Z = 4. The compound with x > 0.5 shows superconductivity with a transition temperature (T_c) 6 K. The compound is a peritectic solid solution associated with other phases such as Mg₉Si₅, Al, and Si, depending on cooling protocols in the preparation. The band structure calculation on the composition MgAlSi suggests that the Al and Mg orbitals mainly contribute to the density of states near the Fermi level, and the substitution of Mg with Al favors the superconductivity.