A Series of [MnMo9O32]6鈥?/sup> Based Solids: Homochiral Transferred from Adjacent Polyoxoanions to One-, Two-, and Three-Dimensional Frameworks

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• 作者：Huaqiao Tan ; Yangguang Li ; Weilin Chen ; Aixue Yan ; Ding Liu ; Enbo Wang
• 刊名：Crystal Growth & Design
• 出版年：2012
• 出版时间：March 7, 2012
• 年：2012
• 卷：12
• 期：3
• 页码：1111-1117
• 全文大小：536K
• 年卷期：v.12,no.3(March 7, 2012)
• ISSN：1528-7505

文摘

Five new compounds based on the Waugh-type polyoxoanion [MnMo₉O₃₂]^{6鈥?/sup> Na₄Mn[MnMo₉O₃₂]路11.5H₂O (1), KNa₃Mn[MnMo₉O₃₂]路9H₂O (2), Na₂Ni₂[MnMo₉O₃₂]路12H₂O (3), l-Mn₃[MnMo₉O₃₂]路13H₂O (4a), d-Mn₃[MnMo₉O₃₂]路13H₂O (4b), and l-Ni₃[MnMo₉O₃₂]路11.5H₂O (5a) have been synthesized. In these compounds, with the changes of Na+/TM (TM = Mn2+, Ni2+) in the crystal, the homochiral interactions were extended from two adjacent [MnMo₉O₃₂]6鈥?/sup> to one-dimensional (compounds 1 and 2), two-dimensional (compound 3), and three-dimensional (compounds 4 and 5) systems, respectively.}