Expedient and Versatile Formation of Novel Amino-deoxy-ketoheptuloses

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• 作者：Yevgeniy Leshch ; Anna Jacobsen ; Julian Thimm ; Joachim Thiem
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：October 4, 2013
• 年：2013
• 卷：15
• 期：19
• 页码：4948-4951
• 全文大小：335K
• 年卷期：v.15,no.19(October 4, 2013)
• ISSN：1523-7052

文摘

Novel monoketoheptuloses have been synthesized employing an amination step in a pre- and/or post-C1 chain elongation using a Petasis reagent by starting from aldohexoses or aldohexosamines. A series of gluco and manno configured 1-/3-deoxy-1-/3-amino-ketohept-2-uloses could be obtained.