ESI-MS Studies on the Mechanism of Pd(0)-Catalyzed Three-Component Tandem Double Addition-Cyclization Reaction

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• 作者：Hao Guo ; Rong Qian ; Yuanxi Liao ; Shengming Ma ; and Yinlong Guo
• 刊名：Journal of the American Chemical Society
• 出版年：2005
• 出版时间：September 21, 2005
• 年：2005
• 卷：127
• 期：37
• 页码：13060 - 13064
• 全文大小：90K
• 年卷期：v.127,no.37(September 21, 2005)
• ISSN：1520-5126

文摘

Four cationic palladium intermediates have been characterized by the high-resolution ESI-FTMS technology, on the basis of which a mechanism was proposed for the Pd(0)-catalyzed three-component tandem double addition cyclization of organic halides, 2-(2,3-allenyl)malonates, and imines.