Ultralong Single-Crystal Metallic Ni2Si Nanowires with Low Resistivity
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  • 作者:Yipu Song ; Andrew L. Schmitt ; Song Jin
  • 刊名:Nano Letters
  • 出版年:2007
  • 出版时间:April 2007
  • 年:2007
  • 卷:7
  • 期:4
  • 页码:965 - 969
  • 全文大小:415K
  • 年卷期:v.7,no.4(April 2007)
  • ISSN:1530-6992
文摘
Ultralong, single-crystal Ni2Si nanowires sheathed with amorphous silicon oxide were synthesized on a large scale by a chemical vaportransport (CVT) method, using iodine as the transport reagent and Ni2Si powder as the source material. Structural characterization usingpowder X-ray diffraction, electron microscopy, and energy-dispersive spectroscopy shows that the nanowires have Ni2Si-SiOx core-shellstructure with single-crystal Ni2Si core and amorphous silicon oxide shell. The oxide shell is electrically insulating and can be removed by HFetching. Four-terminal electrical measurements show that the single-crystal nanowire has extremely low resistivity of 21 ·cm and is capableof supporting remarkably high failure current density >108 A/cm2. These unique Ni2Si nanowires are very attractive nanoscale building blocksfor interconnects and fully silicided (FUSI) gate applications in nanoelectronics.

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