Synthesis and Catalytic Activity of Molybdenum鈥揇initrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
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- 作者：Eriko Kinoshita ; Kazuya Arashiba ; Shogo Kuriyama ; Yoshihiro Miyake ; Ryuji Shimazaki ; Haruyuki Nakanishi ; Yoshiaki Nishibayashi
- 刊名：Organometallics
- 出版年：2012
- 出版时间：December 10, 2012
- 年：2012
- 卷：31
- 期：23
- 页码：8437-8443
- 全文大小：343K
- 年卷期：v.31,no.23(December 10, 2012)
- ISSN：1520-6041
文摘
Novel dinitrogen-bridged dimolybdenum complexes bearing unsymmetric PNP-type pincer ligands are prepared and characterized by X-ray analysis. A molybdenum鈥揹initrogen complex bearing 2-(di-1-adamantylphosphino)methyl-6-(di-tert-butylphosphino)methylpyridine has been found to work as an effective catalyst toward the formation of ammonia from molecular dinitrogen under ambient conditions.