Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines

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• 作者：Masahiro Yuki ; Yoshihiro Miyake ; Yoshiaki Nishibayashi
• 刊名：Organometallics
• 出版年：2012
• 出版时间：April 23, 2012
• 年：2012
• 卷：31
• 期：8
• 页码：2953-2956
• 全文大小：259K
• 年卷期：v.31,no.8(April 23, 2012)
• ISSN：1520-6041

文摘

Novel thiolate-bridged diiron complexes bearing diazenido and diazene ligands in a side-on manner have been prepared and characterized by X-ray analysis. These sulfur-bridged diiron complexes work as effective catalysts toward the reduction of hydrazines into amines and ammonia via a sequential process of protonation and reduction on the sulfur-bridged diiron skeleton, as is likely observed at the active site of nitrogenase.