Nucleophilic Substitution Reaction at the Nitrogen of Arylsulfonamides with Phosphide Anion

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• 作者：Suguru Yoshida ; Kazunobu Igawa ; Katsuhiko Tomooka
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：November 28, 2012
• 年：2012
• 卷：134
• 期：47
• 页码：19358-19361
• 全文大小：306K
• 年卷期：v.134,no.47(November 28, 2012)
• ISSN：1520-5126

文摘

A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.