An Extremely Air-Stable 19蟺 Porphyrinoid

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• 作者：Takuya Yoshida ; Wen Zhou ; Taniyuki Furuyama ; Daniel B. Leznoff ; Nagao Kobayashi
• 刊名：Journal of the American Chemical Society
• 出版年：2015
• 出版时间：July 29, 2015
• 年：2015
• 卷：137
• 期：29
• 页码：9258-9261
• 全文大小：316K
• ISSN：1520-5126

文摘

A one-electron reduced species of a cationic phosphorus(V) tetraazaporphyrin complex has been isolated as an air-stable solid. Cyclic voltammetry and magnetic measurements showed the species to be a neutral 蟺 radical, and the solid state structure was elucidated by single crystal X-ray diffraction analysis. Magnetic circular dichroism spectroscopy and theoretical calculations also support a 19蟺 electron conjugated electronic circuit.