Advances in Synthetic Applications of Hypervalent Iodine Compounds

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• 作者：Akira Yoshimura ; Viktor V. Zhdankin
• 刊名：Chemical Reviews
• 出版年：2016
• 出版时间：March 9, 2016
• 年：2016
• 卷：116
• 期：5
• 页码：3328-3435
• 全文大小：7898K
• 年卷期：Akira Yoshimura, a native of Osaka, Japan, received his M.S. in 2007 and Ph.D. in 2010, both from Tokushima University, under the supervision of Professor Masahito Ochiai. During 2010–2014, he carried out his postdoctoral work with Professor Viktor Zhdankin at University of Minnesota Duluth, and in 2015 he was appointed to a Research Associate position at the same university. His research interests are in the fields of synthetic and mechanistic organic chemistry of hypervalent main-group elements and heterocyclic chemistry. He published 30 research papers, mainly related to the chemistry of hypervalent iodine and bromine.
  Viktor V. Zhdankin was born in Ekaterinburg, Russian Federation. His M.S. (1978), Ph.D. (1981), and Doctor of Chemical Sciences (1986) degrees were earned at Moscow State University. He moved to the University of Utah in 1990, where he worked for three years as Instructor of organic chemistry and Senior Research Associate with Professor Peter J. Stang. In 1993, he joined the faculty of the University of Minnesota Duluth, where he is currently a Professor of Chemistry. He published about 250 research papers, gave over a hundred research presentations in many countries, edited several books, coauthored the Handbook of Heterocyclic Chemistry (3rd ed., 2010), and authored a book on Hypervalent Iodine Chemistry (Wiley, 2013). His main research interests are in the areas of synthetic and mechanistic organic chemistry of hypervalent main-group elements and organofluorine chemistry. In 2011, he was a recipient of the National Award of the American Chemical Society for Creative Research & Applications of Iodine Chemistry. He is a member of the editorial boards of five journals and a Scientific Editor of Arkivoc.
• ISSN：1520-6890

文摘

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed with emphasis on their synthetic application. Compounds of iodine possess reactivity similar to that of transition metals, but have the advantage of environmental sustainability and efficient utilization of natural resources. These compounds are widely used in organic synthesis as selective oxidants and environmentally friendly reagents. Synthetic uses of hypervalent iodine reagents in halogenation reactions, various oxidations, rearrangements, aminations, C–C bond-forming reactions, and transition metal-catalyzed reactions are summarized and discussed. Recent discovery of hypervalent catalytic systems and recyclable reagents, and the development of new enantioselective reactions using chiral hypervalent iodine compounds represent a particularly important achievement in the field of hypervalent iodine chemistry. One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.