Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of Aldimines with Conjugated Dienes Promoted by Diethylzinc
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- 作者：Masanari Kimura ; Atsuko Miyachi ; Keisuke Kojima ; Shuji Tanaka ; and Yoshinao Tamaru
- 刊名：Journal of the American Chemical Society
- 出版年：2004
- 出版时间：November 10, 2004
- 年：2004
- 卷：126
- 期：44
- 页码：14360 - 14361
- 全文大小：96K
- 年卷期：v.126,no.44(November 10, 2004)
- ISSN：1520-5126
文摘
Under the nickel catalysis, in one pot, diethylzinc serves as a reducing agent to connect the three components of 1,3-dienes, alkyl or aryl aldehydes, and anilines to furnish 3-substituted 3,5-syn-5-(arylamino)pent-1-enes 1, the homoallylation products of aldimines with dienes, in excellent yields and with high regio- and stereoselectivity.