A Novel Bilayer Cobalt(II)-Organic Framework with Nanoscale Channels Accommodating Large Organic Molecules

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• 作者：Junhua Luo ; Maochun Hong ; Ruihu Wang ; Rong Cao ; Lei Han ; Daqiang Yuan ; Zhenzhong Lin ; and Youfu Zhou
• 刊名：Inorganic Chemistry
• 出版年：2003
• 出版时间：July 28, 2003
• 年：2003
• 卷：42
• 期：15
• 页码：4486 - 4488
• 全文大小：111K
• 年卷期：v.42,no.15(July 28, 2003)
• ISSN：1520-510X

文摘

A unique noninterpenetrated 2D bilayer cobalt(II)-organic framework, [{Co(dpe)(NO₂-BDC)}·0.5(dpe)]_n·nH₂O (1), possessingnanoscale rectangular channels that clathrate large organicmolecules, has been hydrothermally synthesized by reaction ofcobalt(II) salt with 5-nitro-1,3-benzenedicarboxylic acid (NO₂-H₂BDC) and 1,2-bis(4-pyridyl)ethylene (dpe).