Comparative Stability and Sorption Study of Two the-type Metal–Organic Frameworks with Different Multiplicate Metal–Ligand Interactions in Secondary Building Units

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• 作者：Guoliang Liu ; Bei-Bei Li ; Yan-Xi Tan ; Kongzhao Su ; Daqiang Yuan
• 刊名：Crystal Growth & Design
• 出版年：2017
• 出版时间：February 1, 2017
• 年：2017
• 卷：17
• 期：2
• 页码：418-422
• 全文大小：355K
• ISSN：1528-7505

文摘

By regulating secondary building units and inducing multiplicate metal–ligand interactions, an unstable anionic framework MOF-Mn<sub>4sub>Cl is structurally modified into a robust neutral framework MOF-Mn<sub>4sub>. Although possessing same network topology, MOF-Mn<sub>4sub> shows a high BET surface area of 1718 m<sup>2sup>/g, which is about an 8 times enhancement over MOF-Mn<sub>4sub>Cl.