Electrochemically Controlled Multiple Hydrogen Bonding between Triarylamines and Imidazoles

详细信息    查看全文

• 作者：Hsu-Chun Cheng ; Kuo Yuan Chiu ; Yi-Jung Tu ; Te-Fang Yang ; Yuhlong Oliver Su
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：August 2, 2013
• 年：2013
• 卷：15
• 期：15
• 页码：3868-3871
• 全文大小：306K
• 年卷期：v.15,no.15(August 2, 2013)
• ISSN：1523-7052

文摘

By increasing the number of amino substituents on triarylamine, the extent of hydrogen bonding between the oxidized form of triarylamine and imidazole could be electrochemically controlled. Three behaviors, depending on the interaction between oxidized amine and imidazole, were obtained in CV patterns. DFT calculation was used to confirm that the electron density of protons of the amino group decreased as the amino moiety increased.