PEDOT Encapsulated FeOF Nanorod Cathodes for High Energy Lithium-Ion Batteries

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• 作者：Xiulin Fan ; Chao Luo ; Julia Lamb ; Yujie Zhu ; Kang Xu ; Chunsheng Wang
• 刊名：Nano Letters
• 出版年：2015
• 出版时间：November 11, 2015
• 年：2015
• 卷：15
• 期：11
• 页码：7650-7656
• 全文大小：550K
• ISSN：1530-6992

文摘

Conversion-reaction cathodes can potentially double the energy density of current Li-ion batteries. However, the poor cycling stability, low energy efficiency, and low power density of conversion-reaction cathodes limit their applications for Li-ion batteries. Herein, we report a revolutionary advance in a conversion-reaction cathode by developing a core鈥搒hell FeOF@PEDOT nanorods, in which partial substitution of fluorine with oxygen in FeF₃ substantially enhance the reaction kinetics and reduce the potential hysteresis, while conformal nanolayer PEDOT coating provides a roubst fast electronic connection and prevents the side reactions. The FeOF@PEDOT nanorods deliver a capacity of 560 mA h g^鈥? at 10 mA g^鈥? with an energy density of >1100 W h kg^鈥?, which is more than two times higher than the theoretical energy density of LiCoO₂. The FeOF@PEDOT nanorods can maintain a capacity of 鈭?30 mA h g^鈥? at 50 mA g^鈥? (840 W h kg^鈥?) for over 150 cycles with capacity decay rate of only 0.04% per cycle, which is 2 orders of magnitude lower than the capacity decay rate ever reported among all conversion-reaction cathodes. Detailed characterizations were conducted to identify the structure and mechanism responsible for these significant improvements that could translate into a Li-ion cell with a 2脳 increase in energy density.