Photocatalytic Fuel Cell (PFC) and Dye Self-Photosensitization Photocatalytic Fuel Cell (DSPFC) with BiOCl/Ti Photoanode under UV and Visible Light Irradiation

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• 作者：Kan Li ; Yunlan Xu ; Yi He ; Chen Yang ; Yalin Wang ; Jinping Jia
• 刊名：Environmental Science & Technology (ES&T)
• 出版年：2013
• 出版时间：April 2, 2013
• 年：2013
• 卷：47
• 期：7
• 页码：3490-3497
• 全文大小：445K
• 年卷期：v.47,no.7(April 2, 2013)
• ISSN：1520-5851

文摘

A fuel cell that functioned as a photo fuel cell (PFC) when irradiated with UV light and as a dye self-photosensitization photo fuel cell (DSPFC) when irradiated with visible light was proposed and investigated in this study. The system included a BiOCl/Ti plate photoanode and a Pt cathode, and dye solutions were employed as fuel. Electricity was generated at the same time as the dyes were degraded. 26.2% and 24.4% Coulombic efficiency were obtained when 20 mL of 10 mg路L^鈥? Rhodamine B solution was treated with UV for 2 h and visible light for 3 h, respectively. Irradiation with natural and artificial sunlight was also evaluated. UV and visible light could be utilized at the same time and the photogenerated current was observed. The mechanism of electricity generation in BiOCl/Ti PFC and DSPFC was studied through degradation of the colorless salicylic acid solution. Factors that affect the electricity generation and dye degradation performance, such as solution pH and cathode material, were also investigated and optimized.