Synthetic Tuning of Electronic and Photophysical Properties of 2-Aryl-1,3-Benzothiaphospholes
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- 作者：Joshua C. Worch ; Danielle N. Chirdon ; Andrew B. Maurer ; Yunyan Qiu ; Steven J. Geib ; Stefan Bernhard ; Kevin J. T. Noonan
- 刊名：The Journal of Organic Chemistry
- 出版年：2013
- 出版时间：August 2, 2013
- 年：2013
- 卷：78
- 期：15
- 页码：7462-7469
- 全文大小：382K
- 年卷期：v.78,no.15(August 2, 2013)
- ISSN：1520-6904
文摘
A series of 2-aryl-1,3-benzothiaphospholes have been synthesized from 1-mercapto-2-phosphinobenzene and a variety of acid chlorides. The structure of 2-phenyl-1,3-benzothiaphosphole was established using X-ray diffraction. The electrochemical and photophysical properties of each benzothiaphosphole are reported and some of these molecules exhibit reversible 1-electron reductions.