Influence of the Morphological Characteristics of Separator Membranes on Ionic Mobility in Lithium Secondary Batteries

详细信息    查看全文

• 作者：Yuria SaitoWataru Morimura ; Sadamu Kuse ; Rika Kuratani ; Satoshi Nishikawa
• 刊名：Journal of Physical Chemistry C
• 出版年：2017
• 出版时间：February 9, 2017
• 年：2017
• 卷：121
• 期：5
• 页码：2512-2520
• 全文大小：421K
• ISSN：1932-7455

文摘

Microviscosity components influencing the ionic mobility of lithium electrolyte solution in separator membranes were evaluated and the ionic mobility was correlated with membrane morphology. The microviscosity component responsible for the anion–cation Coulombic interactions (α) was anomalously large in low porosity membranes compared to that in the free electrolyte solution, owing to restricted ionic motion in the narrow pore spaces within the membrane. With increase in the membrane porosity, α diminished owing to the enlarged space and motional freedom for the ionic species, whereas β_cation, which is responsible for the cation/membrane interactions, appeared. This behavior may be due to the specific charge on the walls of the pore spaces and the increased collision frequency for the ions. Consequently, the cationic mobility (D_cation) selectively decreased, whereas the anionic mobility (D_anion) increased in high porosity membranes. Despite the positive correlation between the diffusion coefficient distribution width (σ) and averaged diffusion value for the anion and solvent species, a clear correlation between σ and D_cation was not observed, which is attributed to the fact that the cation is specifically affected by the membrane, perhaps via Coulombic interactions, as evidenced by the appearance of β_cation. Controlling the microviscosities of the ions in the electrolyte by controlling the porous morphology of the separator membrane is significant for designing high-performing battery systems.