First Three-Dimensional Self-Penetrating Coordination Polymer Containing Rare (10,3)-d Subnets: Synthesis, Structure, and Properties

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• 作者：Li-Hui Cao ; Qing-Qing Xu ; Shuang-Quan Zang ; Hong-Wei Hou ; Thomas C. W. Mak
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：May 1, 2013
• 年：2013
• 卷：13
• 期：5
• 页码：1812-1814
• 全文大小：259K
• 年卷期：v.13,no.5(May 1, 2013)
• ISSN：1528-7505

文摘

Hydrothermal assembly of Zn^II ion, a tripodal ligand with both flexible imidazole and rigid carboxylate groups [HL = 3,5-bis(imidazol-1-ylmethyl)benzoic acid hydrochloride], and rigid bidentate linker 5-iodoisophthalic acid (5-iipa) yields a novel three-dimensional (3D) self-penetrating metal鈥搊rganic framework [Zn₂(L)₂(5-iipa)]_n (1). Complex 1 exhibits a (6²路8)(6³路8路10²) topology that is unprecedented with the rare (10,3)-d (or utp) subnets. In addition, photoluminescence was also performed on 1.