The First Slipped Pseudo-Quadruple-Decker Complex of Phthalocyanines
详细信息 查看全文
- 作者：Hongchuan Zhang ; Rongmin Wang ; Peihua Zhu ; Zefeng Lai ; Juan Han ; Chi-Fung Choi ; Dennis K. P. Ng ; Xuegui Cui ; Changqin Ma ; and Jianzhuang Jiang
- 刊名：Inorganic Chemistry
- 出版年：2004
- 出版时间：July 26, 2004
- 年：2004
- 卷：43
- 期：15
- 页码：4740 - 4742
- 全文大小：83K
- 年卷期：v.43,no.15(July 26, 2004)
- ISSN：1520-510X
文摘
The first slipped pseudo-quadruple-decker complex of phthalocyanines was formed unexpectedly upon treatmentof the protonated double-decker SmIIIH(Pc)[Pc(
-OC4H9)8] with NaOH. The supramolecular structure contains twodouble-decker units linked by two sodium ions by an extremely rare coordination mode of phthalocyanines in whichan aza nitrogen atom and two oxygen atoms from neighboring alkoxy substituents form a tridentate ligand.
-OC4H9)8] with NaOH. The supramolecular structure contains twodouble-decker units linked by two sodium ions by an extremely rare coordination mode of phthalocyanines in whichan aza nitrogen atom and two oxygen atoms from neighboring alkoxy substituents form a tridentate ligand.