Preparation of Azafullerene Derivatives from Fullerene-Mixed Peroxides and Single Crystal X-ray Structures of Azafulleroid and Azafullerene

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• 作者：Gaihong Zhang ; Shaohua Huang ; Zuo Xiao ; Quan Chen ; Liangbing Gan ; Zheming Wang
• 刊名：Journal of the American Chemical Society
• 出版年：2008
• 出版时间：September 24, 2008
• 年：2008
• 卷：130
• 期：38
• 页码：12614-12615
• 全文大小：131K
• 年卷期：v.130,no.38(September 24, 2008)
• ISSN：1520-5126

文摘

Azafullerene was prepared by addition of hydroxylamine to a cage-opened fullerendione derivative and subsequent PCl₅ induced rearrangement processes. X-ray structures were obtained for the azafullerene and its azafulleroid precursor.