文摘

In this contribution, we show that the spin−lattice relaxation time, T₁, corresponding to zeolite exchanged molybdenum species in Mo/HZSM-5 catalysts is about 2 orders of magnitude shorter than the corresponding T₁ for small MoO₃ crystallites. Such a difference is utilized to differentiate the exchanged Mo species from MoO₃ agglomerates in Mo/HZSM-5 catalysts and to readily estimate their relative fractions present in catalysts with varying Mo loading. A good linear correlation between the amount of zeolite exchanged species and the aromatics formation rate during catalytic methane dehydroaromatization is obtained. This result significantly strengthens our prior conclusion that the exchanged Mo species are the active centers for this reaction on Mo/HZSM-5 catalysts (J. Am. Chem. Soc. 2008, 130, 3722−3723). Of more general interest for Mo-exchanged zeolites, the results may provide useful data for analyzing the binding of exchanged Mo species in zeolite cages. In particular, the NMR data suggest a possible saturation loading for the exchanged Mo species at a Mo/Al ratio of approximately 0.5 for the ZSM-5 zeolite used in this study (Si/Al = 25). Furthermore, for polycrystalline MoO₃ powder samples, the parameters related to the electric field gradient (EFG) tensor, the chemical shift anisotropy (CSA), and the three Euler angles required to align the CSA principal axis system with the quadrupolar principal axis system are determined by analyzing both the magic angle spinning (MAS) and static ⁹⁵Mo spectra. The new results obtained from this study on MoO₃ powders should help to clarify some of the contradictions in prior literature reports of studies of Mo-containing solids by ⁹⁵Mo NMR.