New Metal−Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response

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• 作者：Tian-Fu Liu ; Jian L ; Zhengang Guo ; Davide M. Proserpio ; Rong Cao
• 刊名：Crystal Growth & Design
• 出版年：2010
• 出版时间：April 7, 2010
• 年：2010
• 卷：10
• 期：4
• 页码：1489-1491
• 全文大小：738K
• 年卷期：v.10,no.4(April 7, 2010)
• ISSN：1528-7505

文摘

An interesting coordination complex based on a designed X ligand has been prepared. It displays a novel 4-connected uninodal net with point symbol (4²·6³·8) and vertex symbol [4.6.4.6.6.10₁₂] which has never been observed in metal−organic frameworks/coordination polymers. Meanwhile, the compound displays intriguing structural features of interpenetration and self-catenation, as well as nonlinear optical properties.