Preparation of Chiral Mesoporous Silica Nanotubes and Nanoribbons Using a Dual-Templating Approach

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• 作者：Yi Li ; Baozong Li ; Zhuojun Yan ; Zeli Xiao ; Zhibin Huang ; Kai Hu ; Sibing Wang ; Yonggang Yang
• 刊名：Chemistry of Materials
• 出版年：2013
• 出版时间：February 12, 2013
• 年：2013
• 卷：25
• 期：3
• 页码：307-312
• 全文大小：382K
• 年卷期：v.25,no.3(February 12, 2013)
• ISSN：1520-5002

文摘

Single-handed helical silica nanotubes and nanoribbons have attracted much attention, due to their potential for applications in asymmetric catalysis and enantioseparation. However, their surface areas are usually lower than 200 m²/g. Herein, single-handed coiled silica nanoribbons with mesopores in their walls were prepared by changing the molar ratio of the chiral low-molecular-weight amphiphiles (LMWAs) and the F127 triblock copolymer, using a dual-templating approach. The obtained samples were characterized using field-emission scanning electron microscopy, transmission electron microscopy, N₂ sorption measurements, and X-ray diffraction. The BET surface area reached 700 m²/g. The pore diameters did not change significantly at different LMWA/F127 triblock copolymer molar ratios. The formation of the coiled mesoporous silica nanoribbons was studied by taking TEM images at different times during the reaction. The results indicated that the morphology and the mesopores were controlled by the chiral LMWAs and the F127 triblock copolymer, respectively. Silica nanotubes with mesopores in their walls could also be prepared using this approach.

Keywords:

mesoporous materials; chirality; silica; nanoribbons; nanotubes