Fast Removal of Cr(VI) from Aqueous Solution Using Cr(VI)-Imprinted Polymer Particles

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• 作者：Delong Kong ; Fan Zhang ; Keyuan Wang ; Zhongqi Ren ; Weidong Zhang
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2014
• 出版时间：March 19, 2014
• 年：2014
• 卷：53
• 期：11
• 页码：4434-4441
• 全文大小：337K
• 年卷期：v.53,no.11(March 19, 2014)
• ISSN：1520-5045

文摘

A novel Cr(VI) ion imprinted polymer (IIP) was proposed for fast removal of Cr(VI) from aqueous solution. 4-Vinylpyridine and N,N-diethylaminoethyl methacrylate were used as functional monomers, and ethylene glycol dimethacrylate and 2,2-azoisobisbutyronitrile were used as cross-linker and initiator in the presence of a binary porogenic solvent. The prepared Cr(VI)-IIPs were characterized by the Fourier transform infrared spectroscopy and scanning electron microscopy. The effects of pH, initial concentration of Cr(VI) in aqueous solution, temperature, and operating time on adsorption were investigated. At the low pH range of 1.5鈥?.5, the adsorption capacities were high. The influence of temperature was slight. The adsorption equilibrium time was within 3 min. The adsorption process followed the pseudo-second-order equation and the Langmuir isotherm model. The maximum adsorption capacity was up to 286.56 mg/g, and the selectivity factors of Cr(VI)/Cu(II), Cr(VI)/Cd(II), and Cr(VI)/Cr(III) were up to 135.78, 145.44, and 69.91, respectively.