Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder

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• 作者：Ya-Xi Huang ; Biao Liu ; Lei Wen ; Xin Zhang ; Wei Sun ; Jun Lin ; Chun-Zuo Huang ; Rong-Chuan Zhuang ; Jin-Xiao Mi ; Jing-Tai Zhao
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：August 19, 2013
• 年：2013
• 卷：52
• 期：16
• 页码：9169-9171
• 全文大小：258K
• 年卷期：v.52,no.16(August 19, 2013)
• ISSN：1520-510X

文摘

Structural assembly from phosphate to germanophosphate by applying germanate as a binder has been achieved. Two isotypic porous compounds, K₃[M^II₄(HPO₄)₂][Ge₂O(OH)(PO₄)₄]路xH₂O (M^II = Fe, Cd; x = 2 for Fe and 3 for Cd, denoted as KFeGePO-1 and KCdGePO-1, respectively), contain a known transition-metal phosphate (TMPO) layer, _{鈭?/sub>²{[M2(HPO4)3]^{2鈥?/sup>}, which is built from chains of trans-edge-sharing MO6 octahedra bridged by MO5 trigonal bipyramids that were further linked and decorated by phosphate tetrahedra. The layers are bound by infinite chains of GeO5(OH) octahedra, resulting in a 3D open-framework structure with 1D 12-ring channels that are occupied by K+ ions and water molecules. The curvature of the TMPO layers and shape of the 12-ring windows can be tuned by the transition metals because of their Jahn鈥揟eller effect.}}