A series of measurements have
been performed at HillAir Force Base to evaluate real-time instruments formeasurements of
black car
bon aerosol and particle-
bound PAHs emitted from spark and ignition compressionvehicles. Vehicles were operated at idle or fast idle inone set of measurements and were placed under load ona dynamometer during the second series. Photoacousticinstruments were developed that operated at a wavelengthof 1047 nm where gaseous interference is negligi
ble,although sensitivity to
black car
bon is good. Compact,efficient, solid-state lasers with direct electronic modulationcapa
bilities are used in these instruments. Black car
bonmeasurements are compared with samples collected on quartzfi
ber filters that were evaluated using the thermal opticalreflectance method. A measure of total particle-
boundPAH was provided
by photoelectric aerosol sensors (PAS)and is evaluated against a sum of PAH mass concentrationso
btained with a filter-denuder com
bination. The PAS had to
be operated with a dilution system held at approximately150
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C for most of the source sampling to prevent spurious
behavior, thus perhaps compromising detection of lighterPAHs. PA and PAS measurements were found to have a highdegree of correlation, perhaps suggesting that the PAScan respond to the polycyclic nature of the
black car
bonaerosol. The PAS to PA ratio for am
bient air in Fresno,CA is 3.7 times as large in winter than in summer months,suggesting that the PAS clearly does respond tocompounds other than BC when the instrument is usedwithout the heated inlet.