Chiral Cu(salen)-Based Metal–Organic Framework for Heterogeneously Catalyzed Aziridination and Amination of Olefins

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• 作者：Yan Liu ; Zijian Li ; Guozan Yuan ; Qingchun Xia ; Chen Yuan ; Yong Cui
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：December 19, 2016
• 年：2016
• 卷：55
• 期：24
• 页码：12500-12503
• 全文大小：292K
• ISSN：1520-510X

文摘

A homochiral 3D porous metal–organic framework was assembled from a chiral dicarboxylic acid-functionalized Cu(salen)-based catalyst and could serve as an efficient heterogeneous catalyst for aziridination and allylic amination of olefins. Besides easy separation and reuse of the catalyst, the chiral framework confinement could impart substrate size selectivity, enhance catalyst activity, and induce product enantioselectivity.