Metal–Ligand Directed Assembly of Layered Cluster-Based Coordination Polymer and Its Solvent-Mediated Structural Transformations

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• 作者：Jian-Jun Zhang ; Yue Zhao ; Sergio Aaró ; n Gamboa ; Abdessadek Lachgar
• 刊名：Crystal Growth & Design
• 出版年：2008
• 出版时间：January 2008
• 年：2008
• 卷：8
• 期：1
• 页码：172 - 175
• 全文大小：1243K
• 年卷期：v.8,no.1(January 2008)
• ISSN：1528-7505

文摘

A two-dimensional (2D) cluster-based coordination polymer with 4,4-net framework was assembled from solution using the metal–ligand directed assembly methodology. The 2D framework undergoes solvent-mediated structural transformations leading to formation of either a three-dimensional hydrogen-bonded framework when using MeOH solution of (Et₄N)⁺ or one-dimensional coordination polymer in the presence of MeOH solution of 4,4′-dipyridyl N,N′-dioxide (dpyo).