Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution and the Utilization of a Continuous Flow Reactor
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- 作者：Wenyu Huang ; Jack Hung-Chang Liu ; Pinar Alayoglu ; Yimin Li ; Cole A. Witham ; Chia-Kuang Tsung ; F. Dean Toste ; Gabor A. Somorjai
- 刊名：Journal of the American Chemical Society
- 出版年：2010
- 出版时间：December 1, 2010
- 年：2010
- 卷：132
- 期：47
- 页码：16771-16773
- 全文大小：131K
- 年卷期：v.132,no.47(December 1, 2010)
- ISSN：1520-5126
文摘
A highly active heterogeneous Pd-nanoparticle catalyst for the intramolecular addition of phenols to alkynes was developed and employed in a continuous flow reaction system. Running the reaction in flow mode revealed reaction kinetics, such as the activation energy and catalyst deactivation, and provides many potential practical advantages.