Fullerene/Cobalt Porphyrin Hybrid Nanosheets with Ambipolar Charge Transporting Characteristics

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• 作者：Takatsugu Wakahara ; Pasquale D鈥橝ngelo ; Kun鈥檌chi Miyazawa ; Yoshihiro Nemoto ; Osamu Ito ; Nobutaka Tanigaki ; Donal D.C. Bradley ; Thomas D. Anthopoulos
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：May 2, 2012
• 年：2012
• 卷：134
• 期：17
• 页码：7204-7206
• 全文大小：258K
• 年卷期：v.134,no.17(May 2, 2012)
• ISSN：1520-5126

文摘

A novel supramolecular nanoarchitecture, comprising C₆₀/Co porphyrin nanosheets, was prepared by a simple liquid鈥搇iquid interfacial precipitation method and fully characterized by means of optical microscopy, AFM, STEM, TEM, and XRD. It is established that the highly crystalline C₆₀/Co porphyrin nanosheets have a simple (1:1) stoichiometry, and when incorporated in bottom-gate, bottom-contact field-effect transistors (FETs), they show ambipolar charge transport characteristics.