Naphthoxanthenyl, a New Stable Phenalenyl Type Radical Stabilized by Electronic Effects

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• 作者：Ommid Anamimoghadam ; Mark D. Symes ; Christoph Busche ; De-Liang Long ; Stuart T. Caldwell ; Cristina Flors ; Santi Nonell ; Leroy Cronin ; G枚tz Bucher
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：June 21, 2013
• 年：2013
• 卷：15
• 期：12
• 页码：2970-2973
• 全文大小：226K
• 年卷期：v.15,no.12(June 21, 2013)
• ISSN：1523-7052

文摘

Naphthoxanthenyl 1 is a new stable phenalenyl-type radical. Electrochemical studies indicate that 1 has two reversible redox processes that occur on comparatively short time scales. Crystals containing 1 can be grown by electrocrystallization, suggesting that they are conductive.