Lewis Base-Catalyzed Reaction of Aziridinofullerene with Ureas for the Preparation of Fulleroimidazolidinones
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- 作者：Meng-Lei Xing ; Xin-Wei Lu ; Chun-Bao Miao ; Jia-Xing Li ; Xiao-Qiang Sun ; Hai-Tao Yang
- 刊名：Journal of Organic Chemistry
- 出版年：2014
- 出版时间：December 5, 2014
- 年：2014
- 卷：79
- 期：23
- 页码：11774-11779
- 全文大小：369K
- ISSN：1520-6904
文摘
The Lewis base-catalyzed double nucleophilic substitution reaction of N-tosylaziridinofullerene with various ureas allows the easy preparation of fulleroimidazolidinones with a high tolerance for functional groups. Alkyl-substituted ureas show better reactivity than aryl-substituted ureas.