Hypervalent Iodine Reagent Mediated Diamination of [60]Fullerene with Sulfamides or Phosphoryl Diamides

详细信息    查看全文

• 作者：Hai-Tao Yang ; Xin-Wei Lu ; Meng-Lei Xing ; Xiao-Qiang Sun ; Chun-Bao Miao
• 刊名：Organic Letters
• 出版年：2014
• 出版时间：November 21, 2014
• 年：2014
• 卷：16
• 期：22
• 页码：5882-5885
• 全文大小：374K
• ISSN：1523-7052

文摘

A hypervalent iodine-promoted intermolecular diamination reactions of C₆₀ with sulfamides or phosphoryl diamides affords two classes of novel C₆₀-fused cyclic sulfamide or phosphoryl diamide derivatives. The reaction between C₆₀ and sulfamides can be effectively controlled to selectively synthesize diamination products or azafulleroids under PhIO/I₂ or PhI(OAc)₂/I₂ conditions, respectively. Moreover, phosphoryl diamides were first used as an amine source in the diamination of alkenes.