Cu(OAc)2-Mediated Reaction of C60 with Ureas for the Preparation of Fulleroimidazolidinones
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- 作者：Hai-Tao Yang ; Yi-Chen Tan ; Yang Yang ; Xiao-Qiang Sun ; Chun-Bao Miao
- 刊名：Journal of Organic Chemistry
- 出版年：2016
- 出版时间：February 5, 2016
- 年：2016
- 卷：81
- 期：3
- 页码：1157-1163
- 全文大小：531K
- ISSN：1520-6904
文摘
The Cu(OAc)2-mediated intermolecular diamination reaction of C60 with ureas allows the concise and efficient preparation of fulleroimidazolidinones involving the cleavage of two N–H bonds and formation of two C–N bonds. Both dialkylated and diarylated fulleroimidazolidinones can be synthesized using this method.