closo-o-Carboranylmethylamine−Pyridine Associations: Synthesis, Characterization, and First Complexation Studies
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- 作者：Vincent Terrasson ; Jos Giner Planas ; Clara Vias ; Francesc Teixidor ; Damien Prim ; Mark E. Light ; Michael B. Hursthouse
- 刊名：Organometallics
- 出版年：2010
- 出版时间：September 27, 2010
- 年：2010
- 卷：29
- 期：18
- 页码：4130-4134
- 全文大小：817K
- 年卷期：v.29,no.18(September 27, 2010)
- ISSN：1520-6041
文摘
The synthesis of new pyridine-substituted carboranylmethylamines is described. The strategy involved mesylation of carboranylmethanols prior to amination reaction and is particularly adapted to the reactivity of o-carborane derivatives bearing a 2-pyridinyl substituent. Preparation and characterization of a corresponding N,N-ligand−palladium complex as well as first results in a Suzuki coupling reaction are illustrated.