Enantiopure Pseudo-C3-Symmetric Titanium Alkoxide with Propeller-Like Chirality

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• 作者：Philip Axe ; Steven D. Bull ; Matthew G. Davidson ; Carly J. Gilfillan ; Matthew D. Jones ; Diane E. J. E. Robinson ; Luke E. Turner ; William L. Mitchell
• 刊名：Organic Letters
• 出版年：2007
• 出版时间：January 18, 2007
• 年：2007
• 卷：9
• 期：2
• 页码：223 - 226
• 全文大小：140K
• 年卷期：v.9,no.2(January 18, 2007)
• ISSN：1523-7052

文摘

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An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of aderived pseudo-C₃-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol.