Fundamentals of Petroleum Residue Cracking Gasification for Coproduction of Oil and Syngas
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- 作者：Yuming Zhang ; Deping Yu ; Wangliang Li ; Yin Wang ; Shiqiu Gao ; Guangwen Xu
- 刊名：Industrial & Engineering Chemistry Research
- 出版年：2012
- 出版时间：November 21, 2012
- 年：2012
- 卷：51
- 期：46
- 页码：15032-15040
- 全文大小：417K
- 年卷期：v.51,no.46(November 21, 2012)
- ISSN：1520-5045
文摘
Vacuum residue (VR) was stepwise converted via catalytic cracking for liquid and coke gasification for hydrogen-rich syngas in a fluidized bed reactor. Silica sand and spent equilibrium FCC (E-FCC) catalyst were used as the catalysts for VR cracking. The liquid yield was about 89 wt % at 568 掳C using silica sand as catalyst and the conversion ratio of heavy fractions was only 55%. About 60 wt % VR was converted into gas and coke over the E-FCC catalyst at 480 掳C, showing that the catalyst had too strong acidity for VR cracking. The E-FCC catalyst was thus modified (aged) with both hydrothermal treatment and impregnation of alkali and alkaline-earth metals (K and Mg) to weaken its acidity and facilitate the liquid oil production. The aged FCC (A-FCC) catalyst exhibited appropriate cracking activity to allow both the expected liquid yield of about 80 wt % and heavy fraction conversion ratio of up to 98 wt %. Steam gasification of the deposited coke on the surface of the A-FCC catalyst resulted in the production of syngas containing CO and H2 content to be about 45 and 42 vol %, respectively.