Interconversion between Platinum(II) and Platinum(0) with Change of pH: Aqueous Reactions of Pt(H)(TPPTS)3+ (TPPTS = P(m-C6H4SO3Na)3<

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• 作者：Derrik S. Helfer and Jim D. Atwood
• 刊名：Organometallics
• 出版年：2002
• 出版时间：January 21, 2002
• 年：2002
• 卷：21
• 期：2
• 页码：250 - 252
• 全文大小：47K
• 年卷期：v.21,no.2(January 21, 2002)
• ISSN：1520-6041

文摘

The oxidation state for platinum complexesof TPPTS can be controlled through variation of the pHof an aqueous solution. Thus Pt(H)(TPPTS)₃⁺ dissolvedin H₂O gives a well-characterized Pt(II)-H complex atneutral or acidic pH but exists as Pt(TPPTS)₃ at pHs/entities/ge.gif">12.