Adsorption Kinetics in Nanoscale Porous Coordination Polymers
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- 作者：Satish K. Nune ; Praveen K. Thallapally ; Benard Peter McGrail ; Harsha V. R. Annapureddy ; Liem X. Dang ; Donghai Mei ; Naveen Karri ; Kyle J. Alvine ; Matthew J. Olszta ; Bruce W. Arey ; Alice Dohnalkova
- 刊名：ACS Applied Materials & Interfaces
- 出版年：2015
- 出版时间：October 7, 2015
- 年：2015
- 卷：7
- 期：39
- 页码：21712-21716
- 全文大小：327K
- ISSN：1944-8252
文摘
Nanoscale porous coordination polymers were synthesized using simple wet chemical method. The effect of various polymer surfactants on colloidal stability and shape selectivity was investigated. Our results suggest that the nanoparticles exhibited significantly improved adsorption kinetics compared to bulk crystals due to decreased diffusion path lengths and preferred crystal plane interaction.