Experimental and Theoretical Evidence for the First Example of an Organolanthanide(II) Compound Having an Indenyl Ligand Bonded to the Metal through the Benzo Ring in 
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- 作者：Shaowu Wang ; Xinliang Tang ; Andres Vega ; Jean-Yves Saillard ; Enhong Sheng ; Gaosheng Yang ; Shuangliu Zhou ; and Zixiang Huang
- 刊名：Organometallics
- 出版年：2006
- 出版时间：May 8, 2006
- 年：2006
- 卷：25
- 期：10
- 页码：2399 - 2401
- 全文大小：105K
- 年卷期：v.25,no.10(May 8, 2006)
- ISSN：1520-6041
文摘
The reaction of 2 equiv of C9H6-1-SiMe3-3-CH2CH2NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N]3Yb-(
-Cl)Li(THF)3 produced a novel ytterbium(II) complex withan indenyl ligand bonded to the metal via the benzo ring with
4 hapticity, [4:2:1-(C5H10NCH2CH2C9H5SiMe3)Li(-Cl)]Yb-(5:1-C5H10NCH2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.
-Cl)Li(THF)3 produced a novel ytterbium(II) complex withan indenyl ligand bonded to the metal via the benzo ring with4 hapticity, [4:2:1-(C5H10NCH2CH2C9H5SiMe3)Li(-Cl)]Yb-(5:1-C5H10NCH2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.